{"id":14925,"date":"2025-01-26T08:23:40","date_gmt":"2025-01-26T08:23:40","guid":{"rendered":"https:\/\/www.epicmicron.com\/?p=14925"},"modified":"2025-01-26T08:23:45","modified_gmt":"2025-01-26T08:23:45","slug":"the-key-role-of-vulcanization-accelerators-in-the-rubber-industry-the-balance-between-processing-safety-and-vulcanization-rate","status":"publish","type":"post","link":"https:\/\/www.epicmicron.com\/vi\/the-key-role-of-vulcanization-accelerators-in-the-rubber-industry-the-balance-between-processing-safety-and-vulcanization-rate\/","title":{"rendered":"Vai tr\u00f2 quan tr\u1ecdng c\u1ee7a ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a trong ng\u00e0nh c\u00f4ng nghi\u1ec7p cao su: S\u1ef1 c\u00e2n b\u1eb1ng gi\u1eefa an to\u00e0n trong qu\u00e1 tr\u00ecnh x\u1eed l\u00fd v\u00e0 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a"},"content":{"rendered":"<figure class=\"wp-block-image size-large\"><img fetchpriority=\"high\" decoding=\"async\" width=\"1024\" height=\"283\" src=\"https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Rubber-Vulcanization-Accelerators-1024x283.webp\" alt=\"\" class=\"wp-image-14926\" srcset=\"https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Rubber-Vulcanization-Accelerators-1024x283.webp 1024w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Rubber-Vulcanization-Accelerators-300x83.webp 300w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Rubber-Vulcanization-Accelerators-768x213.webp 768w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Rubber-Vulcanization-Accelerators-18x5.webp 18w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Rubber-Vulcanization-Accelerators-600x166.webp 600w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Rubber-Vulcanization-Accelerators.webp 1080w\" sizes=\"(max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<p>Trong ng\u00e0nh c\u00f4ng nghi\u1ec7p cao su, <a href=\"https:\/\/en.wikipedia.org\/wiki\/Vulcanization\">l\u01b0u h\u00f3a<\/a> qu\u00e1 tr\u00ecnh n\u00e0y l\u00e0 ch\u00eca kh\u00f3a \u0111\u1ec3 bi\u1ebfn cao su t\u1eeb v\u1eadt li\u1ec7u nh\u1ef1a th\u00e0nh ch\u1ea5t r\u1eafn c\u00f3 \u0111\u1ed9 \u0111\u00e0n h\u1ed3i v\u00e0 \u0111\u1ed9 b\u1ec1n c\u1ee5 th\u1ec3. \u0110\u1ec3 c\u1ea3i thi\u1ec7n hi\u1ec7u su\u1ea5t x\u1eed l\u00fd v\u00e0 hi\u1ec7u qu\u1ea3 l\u01b0u h\u00f3a c\u1ee7a cao su, vi\u1ec7c l\u1ef1a ch\u1ecdn ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a ph\u00f9 h\u1ee3p l\u00e0 r\u1ea5t quan tr\u1ecdng. Vi\u1ec7c l\u1ef1a ch\u1ecdn ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a kh\u00f4ng ch\u1ec9 \u1ea3nh h\u01b0\u1edfng \u0111\u1ebfn t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a cao su m\u00e0 c\u00f2n li\u00ean quan tr\u1ef1c ti\u1ebfp \u0111\u1ebfn &quot;\u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m&quot; c\u1ee7a cao su trong qu\u00e1 tr\u00ecnh x\u1eed l\u00fd (t\u1ee9c l\u00e0 li\u00ean k\u1ebft ch\u00e9o s\u1edbm do l\u00e3o h\u00f3a ozon, l\u00e3o h\u00f3a nhi\u1ec7t, v.v.) v\u00e0 c\u00e1c t\u00ednh ch\u1ea5t c\u01a1 h\u1ecdc cu\u1ed1i c\u00f9ng. B\u00e0i vi\u1ebft n\u00e0y s\u1ebd kh\u00e1m ph\u00e1 t\u00e1c \u0111\u1ed9ng c\u1ee7a c\u00e1c lo\u1ea1i ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a kh\u00e1c nhau \u0111\u1ed1i v\u1edbi qu\u00e1 tr\u00ecnh l\u01b0u h\u00f3a cao su, \u0111\u1eb7c bi\u1ec7t l\u00e0 t\u00e1c \u0111\u1ed9ng c\u1ee7a ch\u00fang \u0111\u1ed1i v\u1edbi &quot;\u0111\u1ed9 an to\u00e0n x\u1eed l\u00fd&quot; (c\u00f2n \u0111\u01b0\u1ee3c g\u1ecdi l\u00e0 &quot;\u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m&quot;) v\u00e0 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a.<\/p>\n\n\n\n<figure class=\"wp-block-gallery has-nested-images columns-default is-cropped wp-block-gallery-1 is-layout-flex wp-block-gallery-is-layout-flex\">\n<figure class=\"wp-block-image size-large\"><img decoding=\"async\" width=\"849\" height=\"336\" data-id=\"14928\" src=\"https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Vulcanization-Rate-1.webp\" alt=\"\" class=\"wp-image-14928\" srcset=\"https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Vulcanization-Rate-1.webp 849w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Vulcanization-Rate-1-300x119.webp 300w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Vulcanization-Rate-1-768x304.webp 768w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Vulcanization-Rate-1-18x7.webp 18w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Vulcanization-Rate-1-600x237.webp 600w\" sizes=\"(max-width: 849px) 100vw, 849px\" \/><\/figure>\n<\/figure>\n\n\n\n<h2 class=\"wp-block-heading\">1. Vai tr\u00f2 c\u01a1 b\u1ea3n c\u1ee7a ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a cao su<\/h2>\n\n\n\n<p>Ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a l\u00e0 th\u00e0nh ph\u1ea7n thi\u1ebft y\u1ebfu trong h\u1ec7 th\u1ed1ng l\u01b0u h\u00f3a cao su. Ch\u00fang t\u0103ng c\u01b0\u1eddng c\u00e1c t\u00ednh ch\u1ea5t v\u1eadt l\u00fd c\u1ee7a cao su b\u1eb1ng c\u00e1ch x\u00fac t\u00e1c ph\u1ea3n \u1ee9ng li\u00ean k\u1ebft ngang gi\u1eefa l\u01b0u hu\u1ef3nh v\u00e0 chu\u1ed7i ph\u00e2n t\u1eed cao su. Ch\u1ee9c n\u0103ng ch\u00ednh c\u1ee7a ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a l\u00e0 t\u0103ng t\u1ed1c qu\u00e1 tr\u00ecnh l\u01b0u h\u00f3a b\u1eb1ng c\u00e1ch t\u1ea1o \u0111i\u1ec1u ki\u1ec7n cho ph\u1ea3n \u1ee9ng li\u00ean k\u1ebft ngang l\u01b0u hu\u1ef3nh, do \u0111\u00f3 \u0111\u1ea1t \u0111\u01b0\u1ee3c hi\u1ec7u \u1ee9ng l\u01b0u h\u00f3a mong mu\u1ed1n \u1edf nhi\u1ec7t \u0111\u1ed9 th\u1ea5p h\u01a1n.<\/p>\n\n\n\n<p>Vi\u1ec7c l\u1ef1a ch\u1ecdn ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a ph\u1ee5 thu\u1ed9c v\u00e0o lo\u1ea1i h\u1ec7 th\u1ed1ng l\u01b0u h\u00f3a \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng, v\u00ec c\u00e1c ch\u1ea5t t\u0103ng t\u1ed1c kh\u00e1c nhau c\u00f3 th\u1ec3 c\u00f3 t\u00e1c \u0111\u1ed9ng kh\u00e1c nhau \u0111\u1ebfn qu\u00e1 tr\u00ecnh l\u01b0u h\u00f3a. D\u1ef1a tr\u00ean c\u1ea5u tr\u00fac h\u00f3a h\u1ecdc v\u00e0 c\u01a1 ch\u1ebf ph\u1ea3n \u1ee9ng c\u1ee7a ch\u00fang, ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c ph\u00e2n lo\u1ea1i th\u00e0nh m\u1ed9t s\u1ed1 nh\u00f3m, ch\u1eb3ng h\u1ea1n nh\u01b0: ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a mercaptan (v\u00ed d\u1ee5: TMTD), ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a disulfide (v\u00ed d\u1ee5: TBBS, MBS, CBS), ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a amin, ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a thiazole (v\u00ed d\u1ee5: MBT, MBTS) v\u00e0 c\u00e1c lo\u1ea1i ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a chuy\u00ean d\u1ee5ng kh\u00e1c.<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>2. Ph\u00e2n lo\u1ea1i ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a v\u00e0 t\u00e1c \u0111\u1ed9ng c\u1ee7a ch\u00fang \u0111\u1ebfn an to\u00e0n ch\u00e1y x\u00e9m<\/strong><\/h2>\n\n\n\n<h3 class=\"wp-block-heading\"><strong>2.1 Ch\u1ea5t t\u0103ng t\u1ed1c Sulfenamide<\/strong><\/h3>\n\n\n\n<p>Ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a sulfenamide ph\u1ed5 bi\u1ebfn nh\u1ea5t trong ng\u00e0nh cao su. Ch\u00fang cung c\u1ea5p \u0111\u1ed9 an to\u00e0n x\u1eed l\u00fd t\u1ed1t v\u00e0 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a v\u1eeba ph\u1ea3i, khi\u1ebfn ch\u00fang tr\u1edf n\u00ean l\u00fd t\u01b0\u1edfng cho c\u00e1c s\u1ea3n ph\u1ea9m cao su c\u00f3 nhi\u1ec1u \u1ee9ng d\u1ee5ng kh\u00e1c nhau. M\u1ed9t t\u00ednh n\u0103ng ch\u00ednh c\u1ee7a ch\u1ea5t t\u0103ng t\u1ed1c sulfenamide l\u00e0 kh\u1ea3 n\u0103ng ng\u0103n ng\u1eeba hi\u1ec7u qu\u1ea3 hi\u1ec7n t\u01b0\u1ee3ng \u201cch\u00e1y x\u00e9m\u201d (t\u1ee9c l\u00e0 li\u00ean k\u1ebft ch\u00e9o s\u1edbm) trong qu\u00e1 tr\u00ecnh l\u01b0u h\u00f3a. Lo\u1ea1i ch\u1ea5t t\u0103ng t\u1ed1c n\u00e0y l\u00e0m ch\u1eadm s\u1ef1 kh\u1edfi \u0111\u1ea7u c\u1ee7a ph\u1ea3n \u1ee9ng l\u01b0u h\u00f3a v\u00e0 t\u0103ng c\u01b0\u1eddng \u0111\u1ed9 an to\u00e0n x\u1eed l\u00fd b\u1eb1ng c\u00e1ch t\u1ea1o th\u00e0nh ch\u1ea5t trung gian ph\u1ea3n \u1ee9ng c\u00f3 th\u1ec3 \u0111i\u1ec1u ch\u1ec9nh.<\/p>\n\n\n\n<p>Ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a sulfenamide c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c ph\u00e2n lo\u1ea1i th\u00e0nh nhi\u1ec1u lo\u1ea1i d\u1ef1a tr\u00ean c\u1ea5u tr\u00fac c\u1ee7a ch\u00fang, bao g\u1ed3m:<\/p>\n\n\n\n<p><strong>CBS (N-cyclohexyl-2-benzothiazole sulfenamide)<\/strong>:Ch\u1ea5t t\u0103ng t\u1ed1c n\u00e0y cung c\u1ea5p kh\u1ea3 n\u0103ng an to\u00e0n ch\u00e1y x\u00e9m ng\u1eafn h\u01a1n trong qu\u00e1 tr\u00ecnh l\u01b0u h\u00f3a nh\u01b0ng l\u1ea1i mang l\u1ea1i t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a nhanh h\u01a1n.<\/p>\n\n\n\n<p><strong>TBBS (N-tert-butyl-2-benzothiazole sulfenamide)<\/strong>: TBBS c\u00f3 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a ch\u1eadm h\u01a1n m\u1ed9t ch\u00fat so v\u1edbi CBS v\u00e0 c\u00f3 kh\u1ea3 n\u0103ng ch\u1ed1ng ch\u00e1y t\u01b0\u01a1ng \u0111\u1ed1i l\u00e2u h\u01a1n.<\/p>\n\n\n\n<p><strong>MBS (N-morpholinyl-2-benzothiazol sulfenamide)<\/strong>:MBS c\u00f3 \u0111\u1ed9 an to\u00e0n ch\u00e1y l\u00e2u h\u01a1n v\u00e0 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a ch\u1eadm h\u01a1n, ph\u00f9 h\u1ee3p v\u1edbi c\u00e1c s\u1ea3n ph\u1ea9m cao su c\u1ea7n th\u1eddi gian x\u1eed l\u00fd l\u00e2u h\u01a1n.<\/p>\n\n\n\n<p><strong>DCBS (N,N-dicyclohexyl-2-benzothiazole sulfenamide)<\/strong>:DCBS cung c\u1ea5p kh\u1ea3 n\u0103ng ch\u1ed1ng ch\u00e1y l\u00e2u nh\u1ea5t v\u00e0 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a ch\u1eadm nh\u1ea5t, l\u00fd t\u01b0\u1edfng cho c\u00e1c s\u1ea3n ph\u1ea9m cao su hi\u1ec7u su\u1ea5t cao c\u1ea7n l\u01b0u h\u00f3a ch\u1eadm h\u01a1n.<\/p>\n\n\n\n<h3 class=\"wp-block-heading\"><strong>2.2 Ch\u1ea5t t\u0103ng t\u1ed1c Thiazole<\/strong><\/h3>\n\n\n\n<p>C\u00e1c ch\u1ea5t t\u0103ng t\u1ed1c thiazole, ch\u1eb3ng h\u1ea1n nh\u01b0 MBT (2-mercaptobenzothiazole) v\u00e0 MBTS (dibenzothiazyl disulfide), c\u0169ng l\u00e0 nh\u1eefng ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a th\u01b0\u1eddng \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng. C\u00e1c ch\u1ea5t t\u0103ng t\u1ed1c n\u00e0y th\u01b0\u1eddng cung c\u1ea5p t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a nhanh h\u01a1n nh\u01b0ng c\u00f3 \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m t\u01b0\u01a1ng \u0111\u1ed1i th\u1ea5p. M\u1eb7c d\u00f9 MBT v\u00e0 MBTS cung c\u1ea5p t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a cao h\u01a1n, nh\u01b0ng ch\u00fang c\u00f3 nhi\u1ec1u kh\u1ea3 n\u0103ng g\u00e2y ra li\u00ean k\u1ebft ch\u00e9o s\u1edbm c\u1ee7a cao su \u1edf nhi\u1ec7t \u0111\u1ed9 cao ho\u1eb7c trong qu\u00e1 tr\u00ecnh x\u1eed l\u00fd, \u0111i\u1ec1u n\u00e0y c\u00f3 th\u1ec3 \u1ea3nh h\u01b0\u1edfng \u0111\u1ebfn kh\u1ea3 n\u0103ng x\u1eed l\u00fd c\u1ee7a cao su.<\/p>\n\n\n\n<p><strong>Xe t\u0103ng chi\u1ebfn \u0111\u1ea5u ch\u1ee7 l\u1ef1c<\/strong>: C\u00f3 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a cao h\u01a1n nh\u01b0ng \u0111\u1ed9 an to\u00e0n ch\u00e1y k\u00e9m, ph\u00f9 h\u1ee3p cho c\u00e1c \u1ee9ng d\u1ee5ng l\u01b0u h\u00f3a nhanh.<\/p>\n\n\n\n<p><strong>MBTS (B\u1ec7nh vi\u1ec7n Nhi khoa)<\/strong>:So v\u1edbi MBT, MBTS c\u00f3 \u0111\u1ed9 an to\u00e0n ch\u1ed1ng ch\u00e1y \u0111\u01b0\u1ee3c c\u1ea3i thi\u1ec7n \u0111\u00f4i ch\u00fat, nh\u01b0ng v\u1eabn \u0111\u01b0\u1ee3c coi l\u00e0 ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a t\u01b0\u01a1ng \u0111\u1ed1i \u201cn\u00f3ng v\u1ed9i\u201d.<\/p>\n\n\n\n<h3 class=\"wp-block-heading\"><strong>2.3 Ch\u1ea5t t\u0103ng t\u1ed1c Thiuram v\u00e0 Dithiocarbamate<\/strong><\/h3>\n\n\n\n<p>C\u00e1c ch\u1ea5t t\u0103ng t\u1ed1c Thiuram v\u00e0 Dithiocarbamate, ch\u1eb3ng h\u1ea1n nh\u01b0 TMTD (Tetramethylthiuram disulfide) v\u00e0 c\u00e1c ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a disulfide kh\u00e1c, c\u00f3 \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m th\u1ea5p h\u01a1n trong qu\u00e1 tr\u00ecnh l\u01b0u h\u00f3a cao su. M\u1eb7c d\u00f9 lo\u1ea1i ch\u1ea5t t\u0103ng t\u1ed1c n\u00e0y cung c\u1ea5p t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a nhanh h\u01a1n, nh\u01b0ng \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m k\u00e9m c\u1ee7a n\u00f3 c\u00f3 th\u1ec3 d\u1ec5 d\u00e0ng d\u1eabn \u0111\u1ebfn li\u00ean k\u1ebft ch\u00e9o s\u1edbm c\u1ee7a cao su trong qu\u00e1 tr\u00ecnh x\u1eed l\u00fd, \u0111i\u1ec1u n\u00e0y c\u00f3 th\u1ec3 \u1ea3nh h\u01b0\u1edfng ti\u00eau c\u1ef1c \u0111\u1ebfn qu\u00e1 tr\u00ecnh \u0111\u00fac v\u00e0 x\u1eed l\u00fd ti\u1ebfp theo.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img decoding=\"async\" width=\"1000\" height=\"1000\" src=\"https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Jet-Mill.webp\" alt=\"\" class=\"wp-image-14930\" srcset=\"https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Jet-Mill.webp 1000w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Jet-Mill-300x300.webp 300w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Jet-Mill-100x100.webp 100w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Jet-Mill-768x768.webp 768w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Jet-Mill-12x12.webp 12w, https:\/\/www.epicmicron.com\/wp-content\/uploads\/2025\/01\/Jet-Mill-600x600.webp 600w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/><\/figure>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>3. M\u1ed1i quan h\u1ec7 gi\u1eefa \u0111\u1ed9 an to\u00e0n ch\u00e1y v\u00e0 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a<\/strong><\/h2>\n\n\n\n<h3 class=\"wp-block-heading\"><strong>3.1 An to\u00e0n ch\u00e1y x\u00e9m<\/strong><\/h3>\n\n\n\n<p>\u0110\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m l\u00e0 kh\u1ea3 n\u0103ng c\u1ee7a cao su duy tr\u00ec tr\u1ea1ng th\u00e1i x\u1eed l\u00fd \u1ed5n \u0111\u1ecbnh trong m\u1ed9t kho\u1ea3ng th\u1eddi gian nh\u1ea5t \u0111\u1ecbnh m\u00e0 kh\u00f4ng tr\u1ea3i qua qu\u00e1 tr\u00ecnh l\u01b0u h\u00f3a s\u1edbm. Vi\u1ec7c l\u1ef1a ch\u1ecdn ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a \u0111\u00f3ng vai tr\u00f2 quan tr\u1ecdng trong \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m. Trong s\u1ea3n xu\u1ea5t th\u1ef1c t\u1ebf, vi\u1ec7c l\u1ef1a ch\u1ecdn ch\u1ea5t t\u0103ng t\u1ed1c c\u00f3 \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m d\u00e0i h\u01a1n \u0111\u1ea3m b\u1ea3o r\u1eb1ng cao su kh\u00f4ng tr\u1ea3i qua qu\u00e1 tr\u00ecnh li\u00ean k\u1ebft ch\u00e9o s\u1edbm trong qu\u00e1 tr\u00ecnh x\u1eed l\u00fd, ng\u0103n ng\u1eeba c\u00e1c v\u1ea5n \u0111\u1ec1 c\u00f3 th\u1ec3 \u1ea3nh h\u01b0\u1edfng \u0111\u1ebfn qu\u00e1 tr\u00ecnh \u0111\u00fac v\u00e0 l\u01b0u h\u00f3a ti\u1ebfp theo. Nh\u00ecn chung, ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a sulfenamide cung c\u1ea5p \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m d\u00e0i h\u01a1n, trong \u0111\u00f3 DCBS l\u00e0 ch\u1ea5t c\u00f3 \u0111\u1ed9 an to\u00e0n d\u00e0i nh\u1ea5t. N\u00f3 \u0111\u1eb7c bi\u1ec7t ph\u00f9 h\u1ee3p v\u1edbi c\u00e1c s\u1ea3n ph\u1ea9m cao su c\u00f3 y\u00eau c\u1ea7u cao h\u01a1n v\u1ec1 \u0111\u1ed9 \u1ed5n \u0111\u1ecbnh trong qu\u00e1 tr\u00ecnh x\u1eed l\u00fd.<\/p>\n\n\n\n<h3 class=\"wp-block-heading\"><strong>3.2 T\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a<\/strong><\/h3>\n\n\n\n<p>T\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a \u0111\u1ec1 c\u1eadp \u0111\u1ebfn t\u1ed1c \u0111\u1ed9 m\u00e0 cao su tr\u1ea3i qua ph\u1ea3n \u1ee9ng li\u00ean k\u1ebft ch\u00e9o trong qu\u00e1 tr\u00ecnh gia nhi\u1ec7t. T\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a nhanh h\u01a1n th\u01b0\u1eddng d\u1eabn \u0111\u1ebfn c\u00e1c \u0111\u1eb7c t\u00ednh v\u1eadt l\u00fd t\u1ed1t h\u01a1n c\u1ee7a cao su (nh\u01b0 \u0111\u1ed9 \u0111\u00e0n h\u1ed3i, kh\u1ea3 n\u0103ng ch\u1ed1ng l\u00e3o h\u00f3a, v.v.). Tuy nhi\u00ean, n\u1ebfu t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a qu\u00e1 nhanh, n\u00f3 c\u00f3 th\u1ec3 g\u00e2y kh\u00f3 kh\u0103n trong vi\u1ec7c \u0111\u00fac c\u00e1c s\u1ea3n ph\u1ea9m cao su trong qu\u00e1 tr\u00ecnh s\u1ea3n xu\u1ea5t. Do \u0111\u00f3, \u0111\u1ea1t \u0111\u01b0\u1ee3c t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a ph\u00f9 h\u1ee3p l\u00e0 r\u1ea5t quan tr\u1ecdng \u0111\u1ed1i v\u1edbi c\u1ea3 qu\u00e1 tr\u00ecnh s\u1ea3n xu\u1ea5t v\u00e0 hi\u1ec7u su\u1ea5t c\u1ee7a s\u1ea3n ph\u1ea9m cu\u1ed1i c\u00f9ng. Lo\u1ea1i v\u00e0 l\u01b0\u1ee3ng ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a c\u00f3 th\u1ec3 \u1ea3nh h\u01b0\u1edfng \u0111\u00e1ng k\u1ec3 \u0111\u1ebfn t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a.<\/p>\n\n\n\n<p><strong>Ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a CBS v\u00e0 TBBS<\/strong>\u00a0ph\u00f9 h\u1ee3p v\u1edbi nh\u1eefng t\u00ecnh hu\u1ed1ng \u0111\u00f2i h\u1ecfi t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a nhanh h\u01a1n v\u00ec ch\u00fang c\u00f3 th\u1ec3 ho\u00e0n th\u00e0nh ph\u1ea3n \u1ee9ng l\u01b0u h\u00f3a m\u1ed9t c\u00e1ch nhanh ch\u00f3ng.<\/p>\n\n\n\n<p><strong>DCBS<\/strong>\u00a0t\u1ed1t h\u01a1n cho c\u00e1c \u1ee9ng d\u1ee5ng y\u00eau c\u1ea7u t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a ch\u1eadm h\u01a1n. Lo\u1ea1i ch\u1ea5t t\u0103ng t\u1ed1c n\u00e0y th\u01b0\u1eddng \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng trong c\u00e1c s\u1ea3n ph\u1ea9m cao su \u0111\u00f2i h\u1ecfi th\u1eddi gian l\u00e0m vi\u1ec7c d\u00e0i h\u01a1n ho\u1eb7c nhi\u1ec7t \u0111\u1ed9 x\u1eed l\u00fd th\u1ea5p h\u01a1n.<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>\u1ea2nh h\u01b0\u1edfng c\u1ee7a vi\u1ec7c l\u1ef1a ch\u1ecdn ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a l\u00ean t\u00ednh ch\u1ea5t c\u1ee7a cao su<\/strong><\/h2>\n\n\n\n<p>C\u00e1c lo\u1ea1i ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a kh\u00e1c nhau kh\u00f4ng ch\u1ec9 \u1ea3nh h\u01b0\u1edfng \u0111\u1ebfn t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a v\u00e0 \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m m\u00e0 c\u00f2n c\u00f3 th\u1ec3 \u1ea3nh h\u01b0\u1edfng \u0111\u1ebfn c\u00e1c t\u00ednh ch\u1ea5t c\u01a1 h\u1ecdc cu\u1ed1i c\u00f9ng (nh\u01b0 \u0111\u1ed9 b\u1ec1n k\u00e9o, \u0111\u1ed9 b\u1ec1n x\u00e9, \u0111\u1ed9 c\u1ee9ng, v.v.) v\u00e0 c\u00e1c \u0111\u1eb7c t\u00ednh hi\u1ec7u su\u1ea5t (nh\u01b0 kh\u1ea3 n\u0103ng ch\u1ed1ng m\u00e0i m\u00f2n, kh\u1ea3 n\u0103ng ch\u1ecbu nhi\u1ec7t \u0111\u1ed9 cao v\u00e0 t\u00ednh ch\u1ea5t ch\u1ed1ng l\u00e3o h\u00f3a) c\u1ee7a cao su. Do \u0111\u00f3, khi l\u1ef1a ch\u1ecdn ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a, \u0111i\u1ec1u quan tr\u1ecdng l\u00e0 ph\u1ea3i xem x\u00e9t kh\u00f4ng ch\u1ec9 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a v\u00e0 \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m m\u00e0 c\u00f2n c\u1ea3 c\u00e1c y\u00eau c\u1ea7u \u1ee9ng d\u1ee5ng cu\u1ed1i c\u00f9ng c\u1ee7a s\u1ea3n ph\u1ea9m cao su.<\/p>\n\n\n\n<p>C\u00e1c ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a c\u00f3 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a nhanh (nh\u01b0 TBBS) ph\u00f9 h\u1ee3p v\u1edbi m\u00f4i tr\u01b0\u1eddng s\u1ea3n xu\u1ea5t \u0111\u00f2i h\u1ecfi t\u1ea1o m\u1eabu nhanh v\u00e0 kh\u1ed1i l\u01b0\u1ee3ng s\u1ea3n xu\u1ea5t l\u1edbn. Tuy nhi\u00ean, ch\u00fang c\u00f3 th\u1ec3 l\u00e0m gi\u1ea3m nh\u1eb9 t\u00ednh ch\u1ea5t c\u01a1 h\u1ecdc c\u1ee7a cao su.<\/p>\n\n\n\n<p>Ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a c\u00f3 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a ch\u1eadm h\u01a1n (nh\u01b0 DCBS) ph\u00f9 h\u1ee3p h\u01a1n v\u1edbi c\u00e1c s\u1ea3n ph\u1ea9m cao su \u0111\u00f2i h\u1ecfi t\u00ednh ch\u1ea5t ch\u1ed1ng l\u00e3o h\u00f3a cao h\u01a1n v\u00e0 hi\u1ec7u su\u1ea5t c\u01a1 h\u1ecdc t\u1ed1t h\u01a1n, \u0111\u1eb7c bi\u1ec7t l\u00e0 trong s\u1ea3n xu\u1ea5t c\u00e1c s\u1ea3n ph\u1ea9m cao su hi\u1ec7u su\u1ea5t cao.<\/p>\n\n\n\n<p>Vi\u1ec7c l\u1ef1a ch\u1ecdn ch\u1ea5t x\u00fac ti\u1ebfn l\u01b0u h\u00f3a cao su \u0111\u00f3ng vai tr\u00f2 quan tr\u1ecdng trong vi\u1ec7c x\u00e1c \u0111\u1ecbnh hi\u1ec7u su\u1ea5t x\u1eed l\u00fd, t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a, \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m v\u00e0 t\u00ednh ch\u1ea5t v\u1eadt l\u00fd cu\u1ed1i c\u00f9ng c\u1ee7a cao su. C\u00e1c lo\u1ea1i ch\u1ea5t x\u00fac ti\u1ebfn kh\u00e1c nhau th\u1ec3 hi\u1ec7n c\u00e1c \u0111\u1eb7c \u0111i\u1ec3m ri\u00eang bi\u1ec7t trong c\u00e1c \u0111i\u1ec1u ki\u1ec7n s\u1ea3n xu\u1ea5t kh\u00e1c nhau. Vi\u1ec7c l\u1ef1a ch\u1ecdn \u0111\u00fang ch\u1ea5t x\u00fac ti\u1ebfn l\u01b0u h\u00f3a c\u00f3 th\u1ec3 n\u00e2ng cao hi\u1ec7u qu\u1ea3 s\u1ea3n xu\u1ea5t v\u00e0 t\u1ed1i \u01b0u h\u00f3a hi\u1ec7u su\u1ea5t c\u1ee7a c\u00e1c s\u1ea3n ph\u1ea9m cao su.<\/p>\n\n\n\n<p>Trong c\u00e1c \u1ee9ng d\u1ee5ng th\u1ef1c t\u1ebf, vi\u1ec7c l\u1ef1a ch\u1ecdn ch\u1ea5t t\u0103ng t\u1ed1c th\u00edch h\u1ee3p c\u00e2n b\u1eb1ng gi\u1eefa t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a v\u00e0 \u0111\u1ed9 an to\u00e0n ch\u00e1y x\u00e9m l\u00e0 ch\u00eca kh\u00f3a \u0111\u1ec3 \u0111\u1ea3m b\u1ea3o c\u1ea3 ch\u1ea5t l\u01b0\u1ee3ng v\u00e0 hi\u1ec7u qu\u1ea3 s\u1ea3n xu\u1ea5t c\u00e1c s\u1ea3n ph\u1ea9m cao su.<\/p>\n\n\n\n<p>\u0110\u1ed1i v\u1edbi c\u00e1c s\u1ea3n ph\u1ea9m cao su th\u00f4ng d\u1ee5ng, ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a sulfenamide \u0111\u01b0\u1ee3c \u01b0a chu\u1ed9ng do t\u00ednh an to\u00e0n khi x\u1eed l\u00fd tuy\u1ec7t v\u1eddi v\u00e0 t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a v\u1eeba ph\u1ea3i. \u0110\u1ed1i v\u1edbi c\u00e1c s\u1ea3n ph\u1ea9m cao su chuy\u00ean d\u1ee5ng, ch\u1eb3ng h\u1ea1n nh\u01b0 cao su hi\u1ec7u su\u1ea5t cao ho\u1eb7c nh\u1eefng s\u1ea3n ph\u1ea9m y\u00eau c\u1ea7u t\u1ed1c \u0111\u1ed9 l\u01b0u h\u00f3a ch\u1eadm h\u01a1n, ch\u1ea5t t\u0103ng t\u1ed1c l\u01b0u h\u00f3a ch\u1eadm nh\u01b0 DCBS l\u00e0 m\u1ed9t l\u1ef1a ch\u1ecdn t\u1ed1t. 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